Carbon dioxide (CO2) is present in a concentration of 0.03% in the atmosphere and is a principal anthropogenic greenhouse gas. For standard use, GHG emissions are measured in one tonne of carbon dioxide equivalent. It is taken as the reference gas against which other greenhouse gases are measured and therefore has a Global Warming Potential of one (1). For example: 1 tonne of Nitrous oxide (N2O) has a GWP of 310, indicating that its radiative forcing is 310 times that of CO2.
Following table shows GWPs of six green house gases:
GHG | Molecular Formula | Atmospheric Lifetime (Years) | Global Warming Potential |
Carbon dioxide | CO2 | 50-200 | 1 |
Methane | CH4 | 12 (+/-3) | 21 |
Nitrous oxide | N2O | 120 | 310 |
Sulphur hexafluoride | SF6 | 3200 | 23900 |
HFC’s | |||
HFC-23 | CHF3 | 264 | 11700 |
HFC-32 | CH2F2 | 5.6 | 650 |
HFC-41 | CH3F | 3.7 | 150 |
HFC-125 | C2HF5 | 32.6 | 2800 |
HFC-134 | C2H2F4 | 10.6 | 1000 |
HFC-134a | C2H3F4 | 14.6 | 1300 |
HFC -143 | C2H3F3 | 3.8 | 300 |
HFC -143a | C2H3F3 | 48.3 | 3800 |
HFC -152a | C2H4F2 | 1.5 | 140 |
HFC -227ea | C3HF7 | 36.5 | 2900 |
HFC -236fa | C3H2F6 | 209 | 6300 |
HFC -245ca | C3H3F5 | 6.6 | 560 |
HFC -4310mee | C5H2F10 | 17.1 | 1300 |
PFCs | |||
PFC-14 | CF4 | 50000 | 6500 |
PFC-116 | C2F2 | 10000 | 9200 |
PFC-218 | C3F8 | 2600 | 7000 |
PFC-3-1-10 | C4F10 | 2600 | 7000 |
PFC-c318 | c-C4F8 | 3200 | 8700 |
PFC-4-1-12 | C5F12 | 4100 | 7500 |
PFC-5-1-14 | C6F14 | 3200 | 7400 |
Source: IPCC Second Assessment Report
a – 100 years time horizon
b- The Methane GWP includes the direct effects and those indirect effects due to the production of tropospheric ozone and stratospheric water vapour. The indirect effect due to the production of CO2 is not included.
Note: The GWP of a GHG accounts for both the immediate radiative forcing due to an increase in the concentration of the gas in the atmosphere, and the lifetime of the gas.
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